William Dougherty, Jr
Associate Professor of Chemistry
Contact Information
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Email Addressdoughertyw@daehanserver.net
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Phone Number570-372-4255
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Office LocationNatural Sciences Center - Rm 307A
I am fortunate in that I knew I wanted to be a chemist from an early age. I found the idea of mixing things together to produce something new fascinating. After I received my first real chemistry set at 13 years old, I was hooked. Even to this day, I still experience the same fascination when I study a chemical process. 把这种感觉传递给下一代科学家的愿望是我来到浩博体育app的原因.
Here at SU, 我能够在课堂上和本科生合作研究中与年轻科学家互动. 苏大的小班授课让我与学生有了更多的个人联系，并为我提供了充足的机会来激发有趣的科学话题的对话.
Through my research, I guide aspiring scientists in the transition from student to researcher, 看着他们在各个领域发展必要的精神和身体技能. I think that’s the greatest thing about a degree in chemistry from a liberal arts college. 中心课程允许学生从各种不同的角度思考问题. 这造就了更好的科学家和毕业生，他们很可能在与专业没有直接关系的职业道路上取得成功. 我本科就读的是一所文理学院，我每天都能感受到这种教育的好处.
When I am not in the classroom or the lab, I enjoy spending time outdoors in the beautiful landscapes surrounding campus.
Research:
The synthesis, characterization, 三吡唑硼酸酯(Tp)配体第一排过渡金属配合物的氧化还原性质.
我们合成了一系列通式为Tp的金属配合物并对其进行了表征PhNi(X)，以确定第4基团X对镍中心氧化还原性能的影响. These complexes have a Ni2+/1+ reduction that can be observed through cyclic voltammetry (CV). 我们目前正在改变Tp配体上的取代，以确定对还原电位的影响.
The synthesis, characterization, and redox properties of first-row transition metal complexes with Janus head ligands.
双面头配体是一类配体，具有两组方向相反的给体原子. 我们感兴趣的是使用这类配体来产生双金属配合物，以研究彼此接近的多种金属的氧化还原性质. 我们目前正在研究苯基双(2-吡啶基)膦与第一排过渡金属的配位化学. 目的是利用这种Janus头配体合成双金属配合物并确定其电化学性质
Support:
Summer ’15 - Susquehanna University Research Partners (本科生资助)“含氨基酸衍生多齿配体的过渡金属配合物的合成与表征”奖:3000美元
Summer ’14 - II-VI基金本科生暑期研究项目“一系列三吡唑酸酯第一排过渡金属配合物的合成及其氧化还原性质”奖励:17美元,764
Publications:
Sevati-Gargari, M.; Mahmoudi, G.; Batton, S.; Stilinovic, V.; Butler, D.; Beauvais, L.; Kassel, W. S.; Dougherty, W. G.; VanDerveer, D. G. 通过改变有机桥接亚基的氢键能力来控制二维MOF-s的互穿 Cryst. Growth Des. 2015, ASAP.
Fang, M.; Wiedner, E. S.; Dougherty, W. G.; Kassel, W. S.; Liu, T.; DuBois, D. L.; Bullock, R. M. 第二配位球含悬垂胺的钴配合物作为制氢电催化剂 Organometallics, 2014, 33, 5820.
Labios, L. A.; Weiss, C. J.; Egbert, J. D.; Lense, S.; Bullock, R. M.; Dougherty, W. G.; Kassel, W. S.; Mock, M. T. 含垂胺的二膦配体负载钼(0)双(二氮)配合物的合成及质子化研究 Z. Anorg. Allg. Chem. 2014, 641, 105.
Becica, J.; Jackson, A. B.; Dougherty, W. G.; Kassel, W. S.; West, N. M. “Bis-tropolonate Complexes of Tungsten,: Scaffolds for Selective Side-on Binding of Nitriles, Imines and Ketones” Dalton Trans. 2014, 43, 8378.
Hosseini-Yazdi, S. A.; Mirzaahmadi, A.; Samadzadeh-Aghdam, P.; Khandar, A. A.; Mahmoudi, G.; Kassel, W. S. Dougherty, W. G. “Synthesis, Characterization, X-ray Structure, 两种新型多齿配体铜锌配合物的光谱和电子学研究 Inorg. Chim. Acta. 2014, 414, 115.
Pagano, J. K.; Sylvester, E. C.; Warnick, E. P.; Dougherty, W. G.; Piro, N. A.; Kassel, W. S.; Nataro, C. “Electrochemical Parameterization of 1,1’-Disubstituted Cobaltocenium Compounds” J. Organomet. Chem. 2014, 750, 107.
Cole, B. E.; Wolbach, J. P.; Dougherty, W. G.; Piro, N. A.; Kassel, W. S.; Graves, C. R. “Synthesis and Characterization of Aluminum-a-diimine Complexes over Multiple Redox States” Inorg. Chem. 2014, 53, 3899Hufziger, K. T.; Thowfeik, F. S.; Charboneau, D. J.; Nieto, I.; Dougherty, W. G.; Kassel, W. S.; Dudley, T. J.; Merino, E. J.; Papish, E. T.; Paul, J. J. 钌二羟基联吡啶配合物是肿瘤激活的前药，由于低pH和蓝光诱导的配体释放.” J. Inorg. Biochem. 2014, 130, 103.
Gramigna, K. M.; Oria, J. V.; Mandell, C. L.; Tiedemann, M. A.; Dougherty, W. G., Piro, N. A.; Kassel, W. S.; Chan, B. C.; Diaconescu, P. L.; Nataro, C. “Palladium(II) and Platinum(II) Compounds of1,1’-Bis(phosphine)metallocene (M= Fe, Ru) Ligands with Metal-Metal Interactions” Organometallics, 2013, 32, 5966.
Wiedner, E. S.; Roberts, J. A. S.; Dougherty, W. G.; Kassel, W. S.; DuBois, D. L.; Bullock, R. M. 含垂胺的钴(III)一氢化物配合物的合成及电化学研究 Inorg. Chem. 2013, 52, 9975.
Mock, M. T.; Chen, S.; O’Hagan, M. J.; Rousseau, R.; Dougherty, W. G.; Kassel, W. S.; Bullock, R. M. 由16元磷大环支撑的铬(0)配合物还原二氮 J. Am. Chem. Soc. 2013, 135, 11493.
Harding, B. A.; Melvin, P. R.; Dougherty Jr., W.; Kassel, S.; Goodson, F. E. “Capturing a Ghost. Synthesis and Structural Characterization of Pd(dba)[P(o-Tol)3]2 Organometallics, 2013, 32, 3570.
Yang, J. Y.; Smith, S. E.; Liu, T.; Dougherty, W. G.; Hoffert, W. A.; Kassel, W. S.; Rakowski DuBois, M.; DuBois, D. L.; Bullock, R. M. 第二配位球中含悬胺的镍双(二膦)配合物电催化氧化氢的两种途径 J. Am. Chem. Soc. 2013, 135, 9700.
Heiden, Z. S.; Chen, S.; Mock, M. T.; Dougherty, W. G.; Kassel, W. S.; Rousseau, R.; Bullock, R. M. 含二膦配体和悬垂胺的二氮铁配合物的质子化作用 Inorg. Chem. 2013, 52, 4026.
Fahey, D. P.; Dougherty, W. G.; Kassel, W. S.; Wang, X.; Beckmann, P. A. “Nonexponential Solid State 1H and 19F Spin-Lattice Relaxation, Single-crystal X-ray Diffraction, 有机固体中分离分子和团簇电子结构的计算:耦合甲基旋转和甲氧基振荡4,4′-Dimethoxyoctafluorobiphenyl.” J. Phys. Chem. A, 2012, 116 (48), 11946.
Fuentes, M. J.; Bognanno, R. J.; Dougherty, W. G.; Boyko, W. J.; Kassel, W.; Dudley, T.; Paul, J. J. “Structural, Electronic and Acid/Base Properties of [Ru(bpy(OH)2)3]2+ (bpy(OH)2 = 4,4’-dihydroxy-2,2’-bipyridine)” Dalton Trans. 2012, 41, 12514.
Dudley, T. J.; Beck, J. E.; Santos, E. E. P.; Johnston, K. A.; Kassel, W. S.; Dougherty, W. G.; Boyko, W. J.; Zubris, D. L. 单(亚胺)吡啶配体异构体的计算和核磁共振分析, 2-{(2,6-Mes-C6H3)NC(iPr)}C5H4N.” RSC Adv. 2012, 2, 6237.
Berstler, J.; Lopez, A.; Menard, D.; Dougherty, W. G.; Kassel, W. S.; Hansen, A.; Daryaei, A.; Ashitey, P.; Shaw, M. J.; Fey, N.; Nataro, C. “Synthesis and spectroelectrochemistry of transition metal carbonyls with 1,1’-bis(phosphino)metallocene ligands” J. Organomet. Chem. 2012, 712, 37.
Weiss, C. J.; Groves, A. M.; Mock, M. T.; Dougherty, W. G.; Kassel, W. S.; Helm, M. L.; DuBois, D. L.; Bullock, R. M. 含垂胺的二膦螯合物负载的钼钨双(二氮)配合物的合成及反应性..” Dalton Trans. 2012, 41,4517.
Wiedner, E. S.; Yang, J. Y.; Chen, S.; Raugei, S.; Dougherty, W. G.; Kassel, W. S.; Helm, M. L.;Bullock, R. M.; Rakowski DuBois, M.; DuBois, D. L. “Stabilization of Nickel Complexes with Ni0···H-N Bonding Interactions Using Sterically Demanding Cyclic Diphosphine Ligands.” Organometallics, 2012, 31,144.
Mock, M. T.; Potter, R. G.; O’Hagan, M. J.; Camaioni, D. M.; Dougherty, W. G.; Kassel, W. S.; DuBois, D. L. “Synthesis and Hydride Transfer Reactions of Cobalt and Nickel Hydride Complexes to BX3 Compounds” Inorg. Chem. 2011, 50, 11914.
Mock, M. T.; Chen, S.; Rousseau, R.; O’Hagan, M. J.; Dougherty, W. G.; Kassel, W. S.; DuBois D. L.; Bullock, R. M. “A Rare Terminal Dinitrogen Complex of Chromium” Chem. Comm. 2011, 47, 12212.
Kilgore, U. J.; Stewart, M. P.; Helm, M. L.; Dougherty, W. G.; Kassel, W. S.; Rakowski DuBois, M.; DuBois, D. L.; Bullock, R. M. “Studies of a Series of [Ni(PR2NPh2)2(CH3CN)]2+ Complexes as Electrocatalysts for H2 Production: Substituent Variation at the Phosphorus Atom of the P2N2 Ligand.” Inorg. Chem. 2011, 50, 10908.
Kulyk, S.; Dougherty Jr., W. G.; Kassel, W. S.; Zdilla, M. J.; Sieburth, S. McN. 分子内吡啶酮/炔光环加成:[4 + 4]和[2 + 2]途径的分配 Org. Lett. 2011, 13, 2180.
Klein, S.; Dougherty, W.; Kassel, W.; Dudley, T.; Paul, J. “Structural, Electronic and Acid/Base Properties of [Ru(bpy)2(bpy(OH)2)]2+ (bpy = 2,2’-bipyridine, bpy(OH)2 = 4,4’-dihydroxy-2,2’-bipyridine)” Inorg. Chem. 2011, 50, 2754.
Kilgore, U.; Roberts, J.; Pool, D.; Appel, A.; Stewart, M.; Rakowski Dubois, M.; Dougherty, W. G.; Kassel, W. S.; Bullock, R. M.; Dubois, D. L. “[Ni(PPh2NPhX2)2](BF4)2 Complexes as Electrocatalysts for H2 Production: Effect of Substituents, Acids, and Water on Catalytic Rates” J. Am. Chem. Soc. 2011, 133, 5861.
Seibert, A. R.; Dougherty, W. G.; Kassel, W. S.; Nataro, C. “Bis(dialkylaminophosphino)ferrocenes : Reactivity and Electrochemistry.” Inorg. Chim. Acta. 2010, 364, 30.
Mandell, C. L.; Kleinbach, W. G.; Dougherty, W. G.; Kassel, W. S.; Nataro, C. “Electrochemistry of FerroTANE and FerroLANE ligands: Free phosphines, metal complexes and chalcogenides.” Inorg. Chem. 2010, 49, 9718.
Yang, J. Y.; Chen, S.; Dougherty, W. G.; Kassel, S.; Bullock, R. M.; Rakowski DuBois, M.; DuBois, D. L.; Raugei, S.; Rousseau, R.; Dupuis, M. “Hydrogen Oxidation Catalysis by a Nickel Diphosphine Complex with Pendant t-Butyl Amines” Chem. Commun. 2010, 46, 8618.
Welch, K. D.; Dougherty, W. G.; Kassel, W. S.; DuBois, D. L.; Bullock, R. M. “Synthesis, Structures, and Reactions of Manganese Complexes Containing Diphosphine Ligands With Pendant Amines” Organometallics 2010, 29, 4532.
Wiedner, E. S.; Yang, J. Y.; Dougherty, W. G.; Kassel, S.; Bullock, R. M.; Rakowski DuBois, M.; DuBois, D. L. 钴和镍配合物与空间要求高的环二膦配体的比较:电催化H2 Production by [Co(PtBu2NPh2)(CH3CN)3](BF4)2” Organometallics 2010, 29, 5390.
Kulyk, S.; Dougherty Jr., W. G.; Kassel, W. S.; Fleming, S. A.; Sieburth, S. McN. “Enyne [4+4] Photocycloaddition: Bridged 1,2,5-Cyclooctatrienes.” Org. Lett. 2010, 12, 3296.
Dougherty, W. G.; Kassel, W. S. 一系列第一排三咪唑基膦夹层配合物的合成及其形成多金属物质的潜力 Inorg. Chim. Acta. 2010, 364, 120. (Invited Contribution : Rheingold Issue)
Sirasani, G.; Paul, T.; Dougherty, W.; Kassel, S.; Andrade, R. “Concise Total Syntheses of (+/-)-Strychnine and (+/-)-Akuammicine” J. Org. Chem. 2010, 75, 3529.
Yang, J. Y.; Bullock, M.; Dougherty, W. G.; Kassel, W. S.; Twamley, B.; DuBois, D. L.; Rakowski Dubois, M. “Reduction of oxygen catalyzed by nickel diphosphine complexes with positioned pendant amines.” Dalton Trans. 2010, 12, 3001.
Popescu, C. V.; Mock, M. T.; Stoian, S. A.; Dougherty, W. G.; Yap, G. P. A.; Riordan, C. G. 高自旋有机金属Fe- s化合物:[苯基三((叔丁基硫)甲基)硼酸盐]Fe(Me)的结构和Mössbauer光谱研究 Inorg. Chem. 2009, 48, 8317.
Mock, M. T.; Potter, R. G.; Camaioni, D. M.; Li, J.; Dougherty, W. G.; Kassel, W. S.; Twamley, B.; DuBois, D. L. “Thermodynamic Studies and Hydride Transfer Reactions from a Rhodium Complex to BX3 Compounds” J. Am. Chem. Soc. 2009, 131, 14454.
Beckmann, P. A.; Dougherty Jr., W. G.; Kassel, W. S. “Methyl and t-butyl reorientation in an organic molecular solid.” Solid State Nucl. Magn. Reson. 2009, 36, 86.
Kahn, S. L.; Breheney, M. K.; Martinak, S. L.; Fosbenner, S. M.; Siebert, A. R.; Kassel, W. S.; Dougherty, W. G.; Nataro, C. “Synthesis, Characterization, and Electrochemistry of Compounds Containing 1-Diphenylphosphino-1’-(di-tert-butylphosphino)ferrocene (dppdtbpf).” Organometallics 2009, 28, 2119.
Steves, J. E.; Kennedy, M. D.; Chiang, K. P.; Kassel, W. S.; Dougherty, W. G.; Dudley, T. J.; Zubris, D. L. 大体积双(亚)吡啶配体的合成:空间体积的系统变化和金属化的能量含义的方法.” Dalton Trans. 2009, 1214.
Axtell, J. A.; Thai, S. D.; Morton, L. A.; Kassel, W. S.; Dougherty, W. G.; Zubris, D. L. “Syntheses of rac/meso-{PhP(3-t-Bu-C5H3)2}-Zr{RN(CH2)3NR}, structural analyses of rac-{PhP(3-t-Bu-C5H3)2}Zr{RN(CH2)3NR} (where R is SiMe3 or Ph), and meso to rac isomerization.” J. Organomet. Chem. 2008, 693, 3741.
Breen, M. E.; Tameze, S. L.; Dougherty, W. G.; Kassel, W. S.; Wheeler, K. A. “Structural Studies of Enantiomers, Racemates, and Quasiracemates. 2-(3-Bromophenoxy)propionic Acid and 2-(3-Methoxyphenoxy)propionic Acid.” Cryst. Growth Des. 2008, 8, 3863.
Dougherty, W.G.; Ragnan, K.; O’Hagen, M.; Yap, G. P. A; Riordan C. G. “Preparation, 含甲基镍的双核配合物的结构和动力学性质:与乙酰辅酶a合成酶催化中有机镍中间体的相关性.” J. Am. Chem. Soc. 2008, 130, 13510.
Mock, M. T.; Popescu, C. V.; Yap, G. P. A.; Dougherty, W. G.; Riordan, C. G. “Monovalent Nickel in a Sulfur-Rich Environment.” Inorg. Chem. 2008, 47, 1889.
Eckert, N. A.; Dougherty, W. G.; Yap, G. P. A.; Riordan, C. G. 甲基钴肟到(三磷)Ni(PPh3)的甲基转移:与乙酰辅酶A合酶的机制相关. ” J. Am. Chem. Soc. 2007, 129, 9286.
DuPont, J. A.; Coxey, M. B.; Schlebler, P. J.; Incarvito, C. D.; Dougherty, W. G., Yap, G. P. A.; Rheingold, A. L.; Riordan, C. G. “High-Spin Organocobalt Complexes in a Thioether Coordination Environment.” Organometallics, 2007, 26, 971.
Kolotilov, S. V.; Addison, A. W.; Trofimenko, S.; Dougherty, W.; Pavlishchuk, V. V; “Efficient mechanochemical synthesis of tris(pyrazolylborate) complexes of manganese(II), cobalt(II) and nickel(II).” Inorg. Chem. Commun. 2004, 7, 485.
- BIOL-450: Advanced STEM Seminar
- CHEM-103: General Chemistry I
- CHEM-103: General Chemistry I: Teams
- CHEM-104: General Chemistry II
- CHEM-105: General Chemistry I Lab
- CHEM-106: General Chemistry II Lab
- CHEM-200: Research Exploration
- CHEM-232: Structure and Reactivity
- CHEM-242: Methods of Chemical Analysis
- CHEM-300: Bioinorganic Chemistry
- CHEM-311: Analytical Chemistry
- CHEM-400: Research Experience
- CHEM-450: Advanced Inorganic Chemistry
- CHEM-500: Problems in Chemistry and Biochemistry
- CHEM-505: Seminar
About Me
I am fortunate in that I knew I wanted to be a chemist from an early age. I found the idea of mixing things together to produce something new fascinating. After I received my first real chemistry set at 13 years old, I was hooked. Even to this day, I still experience the same fascination when I study a chemical process. 把这种感觉传递给下一代科学家的愿望是我来到浩博体育app的原因.
Here at SU, 我能够在课堂上和本科生合作研究中与年轻科学家互动. 苏大的小班授课让我与学生有了更多的个人联系，并为我提供了充足的机会来激发有趣的科学话题的对话.
Through my research, I guide aspiring scientists in the transition from student to researcher, 看着他们在各个领域发展必要的精神和身体技能. I think that’s the greatest thing about a degree in chemistry from a liberal arts college. 中心课程允许学生从各种不同的角度思考问题. 这造就了更好的科学家和毕业生，他们很可能在与专业没有直接关系的职业道路上取得成功. 我本科就读的是一所文理学院，我每天都能感受到这种教育的好处.
When I am not in the classroom or the lab, I enjoy spending time outdoors in the beautiful landscapes surrounding campus.
Professional Experience
Research:
The synthesis, characterization, 三吡唑硼酸酯(Tp)配体第一排过渡金属配合物的氧化还原性质.
我们合成了一系列通式为Tp的金属配合物并对其进行了表征PhNi(X)，以确定第4基团X对镍中心氧化还原性能的影响. These complexes have a Ni2+/1+ reduction that can be observed through cyclic voltammetry (CV). 我们目前正在改变Tp配体上的取代，以确定对还原电位的影响.
The synthesis, characterization, and redox properties of first-row transition metal complexes with Janus head ligands.
双面头配体是一类配体，具有两组方向相反的给体原子. 我们感兴趣的是使用这类配体来产生双金属配合物，以研究彼此接近的多种金属的氧化还原性质. 我们目前正在研究苯基双(2-吡啶基)膦与第一排过渡金属的配位化学. 目的是利用这种Janus头配体合成双金属配合物并确定其电化学性质
Support:
Summer ’15 - Susquehanna University Research Partners (本科生资助)“含氨基酸衍生多齿配体的过渡金属配合物的合成与表征”奖:3000美元
Summer ’14 - II-VI基金本科生暑期研究项目“一系列三吡唑酸酯第一排过渡金属配合物的合成及其氧化还原性质”奖励:17美元,764
Publications:
Sevati-Gargari, M.; Mahmoudi, G.; Batton, S.; Stilinovic, V.; Butler, D.; Beauvais, L.; Kassel, W. S.; Dougherty, W. G.; VanDerveer, D. G. 通过改变有机桥接亚基的氢键能力来控制二维MOF-s的互穿 Cryst. Growth Des. 2015, ASAP.
Fang, M.; Wiedner, E. S.; Dougherty, W. G.; Kassel, W. S.; Liu, T.; DuBois, D. L.; Bullock, R. M. 第二配位球含悬垂胺的钴配合物作为制氢电催化剂 Organometallics, 2014, 33, 5820.
Labios, L. A.; Weiss, C. J.; Egbert, J. D.; Lense, S.; Bullock, R. M.; Dougherty, W. G.; Kassel, W. S.; Mock, M. T. 含垂胺的二膦配体负载钼(0)双(二氮)配合物的合成及质子化研究 Z. Anorg. Allg. Chem. 2014, 641, 105.
Becica, J.; Jackson, A. B.; Dougherty, W. G.; Kassel, W. S.; West, N. M. “Bis-tropolonate Complexes of Tungsten,: Scaffolds for Selective Side-on Binding of Nitriles, Imines and Ketones” Dalton Trans. 2014, 43, 8378.
Hosseini-Yazdi, S. A.; Mirzaahmadi, A.; Samadzadeh-Aghdam, P.; Khandar, A. A.; Mahmoudi, G.; Kassel, W. S. Dougherty, W. G. “Synthesis, Characterization, X-ray Structure, 两种新型多齿配体铜锌配合物的光谱和电子学研究 Inorg. Chim. Acta. 2014, 414, 115.
Pagano, J. K.; Sylvester, E. C.; Warnick, E. P.; Dougherty, W. G.; Piro, N. A.; Kassel, W. S.; Nataro, C. “Electrochemical Parameterization of 1,1’-Disubstituted Cobaltocenium Compounds” J. Organomet. Chem. 2014, 750, 107.
Cole, B. E.; Wolbach, J. P.; Dougherty, W. G.; Piro, N. A.; Kassel, W. S.; Graves, C. R. “Synthesis and Characterization of Aluminum-a-diimine Complexes over Multiple Redox States” Inorg. Chem. 2014, 53, 3899Hufziger, K. T.; Thowfeik, F. S.; Charboneau, D. J.; Nieto, I.; Dougherty, W. G.; Kassel, W. S.; Dudley, T. J.; Merino, E. J.; Papish, E. T.; Paul, J. J. 钌二羟基联吡啶配合物是肿瘤激活的前药，由于低pH和蓝光诱导的配体释放.” J. Inorg. Biochem. 2014, 130, 103.
Gramigna, K. M.; Oria, J. V.; Mandell, C. L.; Tiedemann, M. A.; Dougherty, W. G., Piro, N. A.; Kassel, W. S.; Chan, B. C.; Diaconescu, P. L.; Nataro, C. “Palladium(II) and Platinum(II) Compounds of1,1’-Bis(phosphine)metallocene (M= Fe, Ru) Ligands with Metal-Metal Interactions” Organometallics, 2013, 32, 5966.
Wiedner, E. S.; Roberts, J. A. S.; Dougherty, W. G.; Kassel, W. S.; DuBois, D. L.; Bullock, R. M. 含垂胺的钴(III)一氢化物配合物的合成及电化学研究 Inorg. Chem. 2013, 52, 9975.
Mock, M. T.; Chen, S.; O’Hagan, M. J.; Rousseau, R.; Dougherty, W. G.; Kassel, W. S.; Bullock, R. M. 由16元磷大环支撑的铬(0)配合物还原二氮 J. Am. Chem. Soc. 2013, 135, 11493.
Harding, B. A.; Melvin, P. R.; Dougherty Jr., W.; Kassel, S.; Goodson, F. E. “Capturing a Ghost. Synthesis and Structural Characterization of Pd(dba)[P(o-Tol)3]2 Organometallics, 2013, 32, 3570.
Yang, J. Y.; Smith, S. E.; Liu, T.; Dougherty, W. G.; Hoffert, W. A.; Kassel, W. S.; Rakowski DuBois, M.; DuBois, D. L.; Bullock, R. M. 第二配位球中含悬胺的镍双(二膦)配合物电催化氧化氢的两种途径 J. Am. Chem. Soc. 2013, 135, 9700.
Heiden, Z. S.; Chen, S.; Mock, M. T.; Dougherty, W. G.; Kassel, W. S.; Rousseau, R.; Bullock, R. M. 含二膦配体和悬垂胺的二氮铁配合物的质子化作用 Inorg. Chem. 2013, 52, 4026.
Fahey, D. P.; Dougherty, W. G.; Kassel, W. S.; Wang, X.; Beckmann, P. A. “Nonexponential Solid State 1H and 19F Spin-Lattice Relaxation, Single-crystal X-ray Diffraction, 有机固体中分离分子和团簇电子结构的计算:耦合甲基旋转和甲氧基振荡4,4′-Dimethoxyoctafluorobiphenyl.” J. Phys. Chem. A, 2012, 116 (48), 11946.
Fuentes, M. J.; Bognanno, R. J.; Dougherty, W. G.; Boyko, W. J.; Kassel, W.; Dudley, T.; Paul, J. J. “Structural, Electronic and Acid/Base Properties of [Ru(bpy(OH)2)3]2+ (bpy(OH)2 = 4,4’-dihydroxy-2,2’-bipyridine)” Dalton Trans. 2012, 41, 12514.
Dudley, T. J.; Beck, J. E.; Santos, E. E. P.; Johnston, K. A.; Kassel, W. S.; Dougherty, W. G.; Boyko, W. J.; Zubris, D. L. 单(亚胺)吡啶配体异构体的计算和核磁共振分析, 2-{(2,6-Mes-C6H3)NC(iPr)}C5H4N.” RSC Adv. 2012, 2, 6237.
Berstler, J.; Lopez, A.; Menard, D.; Dougherty, W. G.; Kassel, W. S.; Hansen, A.; Daryaei, A.; Ashitey, P.; Shaw, M. J.; Fey, N.; Nataro, C. “Synthesis and spectroelectrochemistry of transition metal carbonyls with 1,1’-bis(phosphino)metallocene ligands” J. Organomet. Chem. 2012, 712, 37.
Weiss, C. J.; Groves, A. M.; Mock, M. T.; Dougherty, W. G.; Kassel, W. S.; Helm, M. L.; DuBois, D. L.; Bullock, R. M. 含垂胺的二膦螯合物负载的钼钨双(二氮)配合物的合成及反应性..” Dalton Trans. 2012, 41,4517.
Wiedner, E. S.; Yang, J. Y.; Chen, S.; Raugei, S.; Dougherty, W. G.; Kassel, W. S.; Helm, M. L.;Bullock, R. M.; Rakowski DuBois, M.; DuBois, D. L. “Stabilization of Nickel Complexes with Ni0···H-N Bonding Interactions Using Sterically Demanding Cyclic Diphosphine Ligands.” Organometallics, 2012, 31,144.
Mock, M. T.; Potter, R. G.; O’Hagan, M. J.; Camaioni, D. M.; Dougherty, W. G.; Kassel, W. S.; DuBois, D. L. “Synthesis and Hydride Transfer Reactions of Cobalt and Nickel Hydride Complexes to BX3 Compounds” Inorg. Chem. 2011, 50, 11914.
Mock, M. T.; Chen, S.; Rousseau, R.; O’Hagan, M. J.; Dougherty, W. G.; Kassel, W. S.; DuBois D. L.; Bullock, R. M. “A Rare Terminal Dinitrogen Complex of Chromium” Chem. Comm. 2011, 47, 12212.
Kilgore, U. J.; Stewart, M. P.; Helm, M. L.; Dougherty, W. G.; Kassel, W. S.; Rakowski DuBois, M.; DuBois, D. L.; Bullock, R. M. “Studies of a Series of [Ni(PR2NPh2)2(CH3CN)]2+ Complexes as Electrocatalysts for H2 Production: Substituent Variation at the Phosphorus Atom of the P2N2 Ligand.” Inorg. Chem. 2011, 50, 10908.
Kulyk, S.; Dougherty Jr., W. G.; Kassel, W. S.; Zdilla, M. J.; Sieburth, S. McN. 分子内吡啶酮/炔光环加成:[4 + 4]和[2 + 2]途径的分配 Org. Lett. 2011, 13, 2180.
Klein, S.; Dougherty, W.; Kassel, W.; Dudley, T.; Paul, J. “Structural, Electronic and Acid/Base Properties of [Ru(bpy)2(bpy(OH)2)]2+ (bpy = 2,2’-bipyridine, bpy(OH)2 = 4,4’-dihydroxy-2,2’-bipyridine)” Inorg. Chem. 2011, 50, 2754.
Kilgore, U.; Roberts, J.; Pool, D.; Appel, A.; Stewart, M.; Rakowski Dubois, M.; Dougherty, W. G.; Kassel, W. S.; Bullock, R. M.; Dubois, D. L. “[Ni(PPh2NPhX2)2](BF4)2 Complexes as Electrocatalysts for H2 Production: Effect of Substituents, Acids, and Water on Catalytic Rates” J. Am. Chem. Soc. 2011, 133, 5861.
Seibert, A. R.; Dougherty, W. G.; Kassel, W. S.; Nataro, C. “Bis(dialkylaminophosphino)ferrocenes : Reactivity and Electrochemistry.” Inorg. Chim. Acta. 2010, 364, 30.
Mandell, C. L.; Kleinbach, W. G.; Dougherty, W. G.; Kassel, W. S.; Nataro, C. “Electrochemistry of FerroTANE and FerroLANE ligands: Free phosphines, metal complexes and chalcogenides.” Inorg. Chem. 2010, 49, 9718.
Yang, J. Y.; Chen, S.; Dougherty, W. G.; Kassel, S.; Bullock, R. M.; Rakowski DuBois, M.; DuBois, D. L.; Raugei, S.; Rousseau, R.; Dupuis, M. “Hydrogen Oxidation Catalysis by a Nickel Diphosphine Complex with Pendant t-Butyl Amines” Chem. Commun. 2010, 46, 8618.
Welch, K. D.; Dougherty, W. G.; Kassel, W. S.; DuBois, D. L.; Bullock, R. M. “Synthesis, Structures, and Reactions of Manganese Complexes Containing Diphosphine Ligands With Pendant Amines” Organometallics 2010, 29, 4532.
Wiedner, E. S.; Yang, J. Y.; Dougherty, W. G.; Kassel, S.; Bullock, R. M.; Rakowski DuBois, M.; DuBois, D. L. 钴和镍配合物与空间要求高的环二膦配体的比较:电催化H2 Production by [Co(PtBu2NPh2)(CH3CN)3](BF4)2” Organometallics 2010, 29, 5390.
Kulyk, S.; Dougherty Jr., W. G.; Kassel, W. S.; Fleming, S. A.; Sieburth, S. McN. “Enyne [4+4] Photocycloaddition: Bridged 1,2,5-Cyclooctatrienes.” Org. Lett. 2010, 12, 3296.
Dougherty, W. G.; Kassel, W. S. 一系列第一排三咪唑基膦夹层配合物的合成及其形成多金属物质的潜力 Inorg. Chim. Acta. 2010, 364, 120. (Invited Contribution : Rheingold Issue)
Sirasani, G.; Paul, T.; Dougherty, W.; Kassel, S.; Andrade, R. “Concise Total Syntheses of (+/-)-Strychnine and (+/-)-Akuammicine” J. Org. Chem. 2010, 75, 3529.
Yang, J. Y.; Bullock, M.; Dougherty, W. G.; Kassel, W. S.; Twamley, B.; DuBois, D. L.; Rakowski Dubois, M. “Reduction of oxygen catalyzed by nickel diphosphine complexes with positioned pendant amines.” Dalton Trans. 2010, 12, 3001.
Popescu, C. V.; Mock, M. T.; Stoian, S. A.; Dougherty, W. G.; Yap, G. P. A.; Riordan, C. G. 高自旋有机金属Fe- s化合物:[苯基三((叔丁基硫)甲基)硼酸盐]Fe(Me)的结构和Mössbauer光谱研究 Inorg. Chem. 2009, 48, 8317.
Mock, M. T.; Potter, R. G.; Camaioni, D. M.; Li, J.; Dougherty, W. G.; Kassel, W. S.; Twamley, B.; DuBois, D. L. “Thermodynamic Studies and Hydride Transfer Reactions from a Rhodium Complex to BX3 Compounds” J. Am. Chem. Soc. 2009, 131, 14454.
Beckmann, P. A.; Dougherty Jr., W. G.; Kassel, W. S. “Methyl and t-butyl reorientation in an organic molecular solid.” Solid State Nucl. Magn. Reson. 2009, 36, 86.
Kahn, S. L.; Breheney, M. K.; Martinak, S. L.; Fosbenner, S. M.; Siebert, A. R.; Kassel, W. S.; Dougherty, W. G.; Nataro, C. “Synthesis, Characterization, and Electrochemistry of Compounds Containing 1-Diphenylphosphino-1’-(di-tert-butylphosphino)ferrocene (dppdtbpf).” Organometallics 2009, 28, 2119.
Steves, J. E.; Kennedy, M. D.; Chiang, K. P.; Kassel, W. S.; Dougherty, W. G.; Dudley, T. J.; Zubris, D. L. 大体积双(亚)吡啶配体的合成:空间体积的系统变化和金属化的能量含义的方法.” Dalton Trans. 2009, 1214.
Axtell, J. A.; Thai, S. D.; Morton, L. A.; Kassel, W. S.; Dougherty, W. G.; Zubris, D. L. “Syntheses of rac/meso-{PhP(3-t-Bu-C5H3)2}-Zr{RN(CH2)3NR}, structural analyses of rac-{PhP(3-t-Bu-C5H3)2}Zr{RN(CH2)3NR} (where R is SiMe3 or Ph), and meso to rac isomerization.” J. Organomet. Chem. 2008, 693, 3741.
Breen, M. E.; Tameze, S. L.; Dougherty, W. G.; Kassel, W. S.; Wheeler, K. A. “Structural Studies of Enantiomers, Racemates, and Quasiracemates. 2-(3-Bromophenoxy)propionic Acid and 2-(3-Methoxyphenoxy)propionic Acid.” Cryst. Growth Des. 2008, 8, 3863.
Dougherty, W.G.; Ragnan, K.; O’Hagen, M.; Yap, G. P. A; Riordan C. G. “Preparation, 含甲基镍的双核配合物的结构和动力学性质:与乙酰辅酶a合成酶催化中有机镍中间体的相关性.” J. Am. Chem. Soc. 2008, 130, 13510.
Mock, M. T.; Popescu, C. V.; Yap, G. P. A.; Dougherty, W. G.; Riordan, C. G. “Monovalent Nickel in a Sulfur-Rich Environment.” Inorg. Chem. 2008, 47, 1889.
Eckert, N. A.; Dougherty, W. G.; Yap, G. P. A.; Riordan, C. G. 甲基钴肟到(三磷)Ni(PPh3)的甲基转移:与乙酰辅酶A合酶的机制相关. ” J. Am. Chem. Soc. 2007, 129, 9286.
DuPont, J. A.; Coxey, M. B.; Schlebler, P. J.; Incarvito, C. D.; Dougherty, W. G., Yap, G. P. A.; Rheingold, A. L.; Riordan, C. G. “High-Spin Organocobalt Complexes in a Thioether Coordination Environment.” Organometallics, 2007, 26, 971.
Kolotilov, S. V.; Addison, A. W.; Trofimenko, S.; Dougherty, W.; Pavlishchuk, V. V; “Efficient mechanochemical synthesis of tris(pyrazolylborate) complexes of manganese(II), cobalt(II) and nickel(II).” Inorg. Chem. Commun. 2004, 7, 485.